Diffusion and interdiffusion in binary metallic melts
نویسندگان
چکیده
منابع مشابه
Relation between self diffusion and interdiffusion in Al-Cu melts
We compare the experimental interdiffusion constants DAlCu in liquid Al81.3Cu18.7 at% to the experimental Cu self diffusion constants DCu in a similar Al80Cu20 at% melt. DAlCu are measured by an X-ray radiography technique and DCu are measured by the quasielastic neutron scattering method. It was found that DAlCu is enhanced by a factor of 3 with respect to DCu. The relation between DAlCu and D...
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The distinctive features of limited solubility in liquid eutectic and monotectic metallic systems have been discovered. The monodispersed emulsion model has been elaborated for a description of the specific microheterogeneous structure of eutectic melts. It includes the transitional shells (TS) at the interface boundaries having the eutectic composition and the closest packing of atoms. By mean...
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We report the first experimental study of the diffusion of H2O in dacitic melts. Dehydration experiments were conducted at 551–637 8C and 1–1450 bars for samples with ~0.8 to ~2.5 wt.% total dissolved H2O. The H2O diffusivity is proportional to total H2O contents at V0.8 wt.%, but increases exponentially with total H2O at higher H2O contents. The diffusivity of the total dissolved H2O (in Am /s...
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The diffusion of water in dacitic and andesitic melts was investigated at temperatures of 1458 to 1858 K and pressures between 0.5 and 1.5 GPa using the diffusion couple technique. Pairs of nominally dry glasses and hydrous glasses containing between 1.5 and 6.3 wt.% dissolved H2O were heated for 60 to 480 s in a piston cylinder apparatus. Concentration profiles of hydrous species (OH groups an...
متن کاملNon-Equilibrium Solidification of Undercooled Metallic Melts
If a liquid is undercooled below its equilibrium melting temperature an excess Gibbs free energy is created. This gives access to solidification of metastable solids under non-equilibrium conditions. In the present work, techniques of containerless processing are applied. Electromagnetic and electrostatic levitation enable to freely suspend a liquid drop of a few millimeters in diameter. Hetero...
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ژورنال
عنوان ژورنال: Physical Review B
سال: 2014
ISSN: 1098-0121,1550-235X
DOI: 10.1103/physrevb.90.024309